Behaviour of Real Gases

IMPORTANT

Behaviour of Real Gases: Overview

This topic covers concepts, such as, Real Gas, Deviations from Ideal Gas Behaviour, Expression of Critical Pressure & Expression of Critical Volume etc.

Important Questions on Behaviour of Real Gases

HARD
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The pressure exerted by 1 mole of CO2 at 273 K, is 34.98 atm. Assuming that volume occupied by CO2 molecules is negligible, the value of van der Waals' constant for attraction of CO2 gas is :

MEDIUM
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A gas is said to behave like an ideal gas when relation PVT=constant. When do you expect real gas to behave like an ideal gas?

EASY
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In Van der Waal’s equation of state for a non-ideal gas, the term that accounts for intermolecular forces is:

MEDIUM
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Van der Waal’s real gas, act as an ideal gas, at which conditions ?

EASY
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At which one of the following temperature – pressure conditions the deviation of a gas from ideal behaviour is expected to be minimum ?

EASY
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When deviation is more in the behaviour of a gas from the ideal gas equation PV = nRT ?

EASY
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An ideal gas can’t be liquefied because

MEDIUM
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Gases deviate from ideal behaviour at high pressures because the gas molecules

HARD
IMPORTANT

Calculate molecular diameter (in nanometer) for a gas if its molar excluded volume is 3.2π ml. Give the answer by multiplying with 10.

(TakeNA=6.0×1023 

EASY
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The cascade method is used to liquify

EASY
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The Andrew's experiment is the test for the validity of 

EASY
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Identify the postulate of kinetic molecular theory of gases which does not hold good under all conditions.

EASY
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Identify the postulate of kinetic molecular theory of gases which does not hold good under all conditions.

MEDIUM
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The critical volume of a gas is 0.036 l.mol1 . What will be the radius of the molecule in cm?

MEDIUM
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The radius of a molecule is 1.5×10-8 cm. Calculate the critical volume of the gas.

MEDIUM
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The critical volume of a gas is 0.072 l.mol1 . What will be the radius of the molecule in cm?

EASY
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What is critical volume? Give its formula.

MEDIUM
IMPORTANT

Which gas among the following is the easiest to liquify?

EASY
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Among the following, Van der Waals constant 'a' would be maximum for _____

EASY
IMPORTANT

Among the following, the incorrect statement is: